55119-14-7 Usage
Uses
Used in Organic Synthesis:
2,3-DIHYDRO-1H-INDEN-5-YL HYDROSULFIDE is used as a reagent in organic synthesis for its ability to participate in various chemical reactions, such as thiol-ene click reactions. Its strong nucleophilic nature makes it a valuable component in the formation of new chemical bonds and the synthesis of complex organic molecules.
Used as a Precursor for Sulfur-Containing Compounds:
In the field of chemical research and development, 2,3-DIHYDRO-1H-INDEN-5-YL HYDROSULFIDE serves as a precursor for the synthesis of sulfur-containing compounds. Its role is crucial in creating compounds that have specific applications in various industries, including pharmaceuticals and materials science.
Used in the Perfume Industry:
2,3-DIHYDRO-1H-INDEN-5-YL HYDROSULFIDE is also utilized as a fragrance ingredient in the perfume industry. Its unique odor profile contributes to the creation of distinct scents in perfumes and other fragranced products.
Used in Laboratory Research:
As a laboratory reagent, 2,3-DIHYDRO-1H-INDEN-5-YL HYDROSULFIDE is employed in various research applications. Its strong reducing properties make it suitable for experiments that require the reduction of certain chemical species or the facilitation of specific reaction pathways.
Check Digit Verification of cas no
The CAS Registry Mumber 55119-14-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,1,1 and 9 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 55119-14:
(7*5)+(6*5)+(5*1)+(4*1)+(3*9)+(2*1)+(1*4)=107
107 % 10 = 7
So 55119-14-7 is a valid CAS Registry Number.
InChI:InChI=1/C9H10S/c10-9-5-4-7-2-1-3-8(7)6-9/h4-6,10H,1-3H2
55119-14-7Relevant academic research and scientific papers
RADIKALIONEN 89. EINELEKTRONEN-OXIDATIONEN VON DIARYLDISULFIDEN MIT AlCl3/H2CCl2
Bock, Hans,Rittmeyer, Peter
, p. 261 - 292 (2007/10/02)
The single electron oxidation of 14 alkyl and alkoxy substituted diaryldisulfides by AlCl3/H2CCl2 has been investigated by ESR/ENDOR spectroscopy.The radical cations observed prove the following skeletal rearrangements: Those with ring hydrogens in ortho positions to the disulfide bridge preferentially form thianthrene derivatives.The isomeric dinaphthyl disulfides react differently, the 2,2'-isomer yielding the dibenzothianthrene radical cation and the 1,1'-isomer the well-known naphthalene-1,8-disulfide radical cation.For all diaryl disulfides with completely alkyl- or methoxy-blocked ortho positions, oxidative desulfuration is observed.As substantiated by additional (2)D and (33)S isotope marking, the bis(2,5-dimethoxyphenyl)disulfide reacts both to the corresponding thianthrene derivative as well as via desulfuration to the radical cation of the monosulfide.Accompanying cyclovoltammetric and photoelectron spectroscopic measurements prove that all ESR spectroscopically detected radical cations result from compounds Ar-S-Ar, Ar-SS-Ar and Ar(S)2Ar with rather low oxidation or ionisation potentials and thus suggest that each the most easily oxidized paramagnetic species is observed in the rather complex product mixtures, which form on AlCl3/H2CCl2 oxidation of diaryldisulfides. Key words: Diaryl disulfides; one-electron oxidation; radical cations; ESR/ENDOR spectra.
