55168-32-6

Usage

Preparation

Preparation by Fries rearrangement of p-n-hexylphenyl acetate with aluminium chloride without solvent (15%).

Upstream product

• 63446-76-4 1-methyl-1,3-bis(trimethylsilyloxy)buta-1,3-diene 
• 59855-08-2 2-diethoxymethyl-1,1-diethoxyoctane 
• 55168-28-0 p-n-Hexylphenylacetat 

Downstream Products

• 1612141-63-5 C₁₇H₂₆O₃ 
• 1612141-65-7 (S)-4-hexyl-2-(2-methyl-1,3-dioxan-2-yl)-phenyl 2-methoxypropanoate 

Relevant academic research and scientific papers

Improved fuel markers

There is provided a compound comprising the general structure (I) in which, X is N or O; R3 is OR4 or R4; wherein when X is N, R1 is H, R5 or OR6; R2 is OC(O)R7; and R

IMPROVED FUEL MARKERS

There is provided a compound comprising the general structure (I) in which, X is N or O; R3 is OR4 or R4; wherein when X is N, R1 is H, R5 or OR6; R2 is OC(O)R7; and R

Regioselective synthesis of 5-alkylsalicylates, 5-alkyl-2-hydroxy- acetophenones, and 5-alkyl-2-hydroxy-benzophenones by [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 2-alkyl-1,1,3,3-tetraethoxypropanes

(Chemical Equation Presented) A variety of 5-alkylsalicylates, 5-alkyl-2-hydroxy-acetophenones, and 5-alkyl-2-hydroxy-benzophenones was regioselectively prepared by TiCl4 mediated formal [3 + 3] cyclization of 1,3-bis(silyl enol ethers) with 2-alkyl-1,1,3,3- tetraethoxypropanes.