55182-38-2Relevant academic research and scientific papers
A multifunction Pd/Sc(OTf)3/ionic liquid catalyst system for the tandem one-pot conversion of phenol to ε-caprolactam
Shin, Ju Yeon,Jung, Da Jung,Lee, Sang-Gi
, p. 525 - 528 (2013)
A multifunction Pd/Sc(OTf)3/ionic liquid catalyst for the tandem one-pot conversion of phenol to ε-caprolactam is reported. Pd and Sc(OTf)3 cooperate to catalyze the hydrogenation of phenol to cyclohexanone with excellent conversion (>99.9%) and selectivity (>99.9%), whereas Sc(OTf)3 and an ionic liquid, [bmim][PF6], cooperate to catalyze the tandem transformation of the resulting cyclohexanone to cyclohexanone oxime and the Beckmann rearrangement affording ε-caprolactam.
Raney Ni-Al alloy-mediated reduction of alkylated phenols in water
Tan, Song-Liang,Liu, Guo-Bin,Gao, Xiang,Thiemann, Thies
experimental part, p. 5 - 7 (2009/09/06)
Raney Ni-Al alloy in a dilute aqueous alkaline solution has been shown to be a very powerful reducing agent in the hydrogenation of phenol and alkylated phenols to the corresponding cyclohexanol derivatives.
Novel cuticular hydrocarbons from the cane beetle Antitrogus parvulus - 4,6,8,10,16-penta- and 4,6,8,10,16,18-hexamethyldocosanes. Unprecedented anti-anti-anti-stereochemistry in the 4,6,8,10-methyltetrad
Chow, Sharon,Fletcher, Mary T.,Lambert, Lynette K.,Gallagher, Oliver P.,Moore, Christopher J.,Cribb, Bronwen W.,Allsopp, Peter G.,Kitching, William
, p. 1808 - 1827 (2007/10/03)
(Chemical Equation Presented) The major cuticular hydrocarbons from the cane beetle species Antitrogus parvulus are 4,6,8,10,-16-penta- and 4,6,8,10,16,18-hexamethyldocosanes, 1 and 2, respectively. Stereoisomers of 2,4,6,8-tetramethylundecanal of establi
