5523-99-9

Basic information

• Product Name: N-(5-chloro-2,4-dimethoxyphenyl)pyridine-3-carboxamide
• CAS NO: 5523-99-9
• Molecular Formula: C₁₄H₁₃ClN₂O₃
• Molecular Weight: 292.7176
• Mol File: 5523-99-9.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 370.7°C at 760 mmHg
• Flash Point: 178°C
• Density: 1.321g/cm³
• Vapor Pressure: 1.08E-05mmHg at 25°C
• Refractive Index: 1.613
• CAS DataBase Reference: N-(5-chloro-2,4-dimethoxyphenyl)pyridine-3-carboxamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(5-chloro-2,4-dimethoxyphenyl)pyridine-3-carboxamide(5523-99-9)
• EPA Substance Registry System: N-(5-chloro-2,4-dimethoxyphenyl)pyridine-3-carboxamide(5523-99-9)

Safety Data

• Hazardous Substances Data: 5523-99-9(Hazardous Substances Data)

Upstream product

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Relevant articles and documents

Iron-catalyzed oxidative functionalization of C(sp3)-H bonds under bromide-synergized mild conditions

An efficient oxidation and functionalization of C-H bonds with an inorganic-ligand supported iron catalyst and hydrogen peroxide to prepare the corresponding ketones was achieved using the bromide ion as a promoter. Preliminary mechanistic investigations indicated that the bromide ion can bind to FeMo6 to form a supramolecular species (FeMo6·2Br), which can effectively catalyze the reaction.

AN INVESTIGATION OF THE ELECTRON TRANSFER PROPERTIES OF MODIFIED ORGANOCOPPER REAGENTS AND HIGHER-ORDER CUPRATES

The electron transfer properties of organocopper reagents are attenuated on introduction of BF3OEt2 or Me3SiCl.The results are interpreted in concordance with current mechanistic proposals.Higher-order CuCN-based cuprates show significant electron transfer ability, in contrast to the related lower-order cuprates.