553667-76-8Relevant articles and documents
Reactions of elongated dihydrogen-osmium complexes containing orthometalated ketones with alkynes: Hydride-vinylidene-π-alkyne versus hydride-osmacyclopropene
Barrio, Pilar,Esteruelas, Miguel A.,Onate, Enrique
, p. 2472 - 2485 (2003)
In this paper, the preparation and characterization of new organometallic compounds, elongated dihydrogen complexes containing metal -σ carbon bonds allows access to highly unsaturated monohydride intermediates. The alkyne acting as the substituent R, res