553683-61-7Relevant academic research and scientific papers
Mn-mediated oxidative radical cyclization of 2-(azidomethyl)phenyl isocyanides with carbazate: access to quinazoline-2-carboxylates
Begum, Noor Shahina,Mohammed Imran, Khan,Yogesh Kumar, Gujjenahalli Ramalingaiah
supporting information, p. 7001 - 7006 (2020/05/16)
Mn-TBHP mediated oxidative radical cyclization of 2-(azidomethyl)phenyl isocyanides using methyl carbazate has been described. This procedure is realized through a cascade radical addition and aromatization process with high atom economy to furnish various heterocyclic C2 diversified quinazoline-2-carboxylate derivatives.
A convenient synthesis of 2-substituted indoles by the reaction of 2-(chloromethyl)phenyl isocyanides with organolithiums
Kobayashi, Kazuhiro,Iitsuka, Daisuke,Fukamachi, Shuhei,Konishi, Hisatoshi
experimental part, p. 7523 - 7526 (2009/12/04)
The reaction of 2-(chloromethyl)phenyl isocyanides, readily available by dehydration of the respective N-[2-(chloromethyl)phenyl]formamides, with organolithiums produced 2-substituted indoles in satisfactory yields through addition of organolithiums to th
