55425-73-5 Usage
Uses
Used in Chemical Synthesis:
TRIS(DIBUTYLSULFIDE)RHODIUM TRICHLORIDE is used as a catalyst for various organic synthesis reactions, facilitating the production of fine chemicals. Its unique chemical properties and reactivity make it a promising candidate for the development of new materials and technologies.
Used in Organometallic Chemistry:
In the field of organometallic chemistry, TRIS(DIBUTYLSULFIDE)RHODIUM TRICHLORIDE is utilized as a catalyst to enhance the efficiency and selectivity of chemical transformations, contributing to the advancement of research and development in this area.
Used in Industrial Chemical Processes:
TRIS(DIBUTYLSULFIDE)RHODIUM TRICHLORIDE is employed in industrial chemical processes to improve the efficiency and selectivity of reactions, leading to the production of high-quality chemicals and materials.
Used in Material Development:
Due to its unique chemical properties, TRIS(DIBUTYLSULFIDE)RHODIUM TRICHLORIDE has been investigated for its potential application in the development of new materials, with the aim of creating innovative technologies and products.
Check Digit Verification of cas no
The CAS Registry Mumber 55425-73-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,4,2 and 5 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 55425-73:
(7*5)+(6*5)+(5*4)+(4*2)+(3*5)+(2*7)+(1*3)=125
125 % 10 = 5
So 55425-73-5 is a valid CAS Registry Number.
InChI:InChI=1/3C8H18S.3ClH.Rh/c3*1-3-5-7-9-8-6-4-2;;;;/h3*3-8H2,1-2H3;3*1H;/q;;;;;;+3/p-3/r3C8H18S.Cl3Rh/c3*1-3-5-7-9-8-6-4-2;1-4(2)3/h3*3-8H2,1-2H3;
55425-73-5Relevant academic research and scientific papers
Olsen, Matthew T.,Rekken, Brian D.,Eldred, Donald V.
, p. 4484 - 4494 (2017)
RhCl3(Bu2S)3 is an industrial precatalyst utilized in the curing of some solventless silicone-release coatings formulations. The catalyst requires no additional inhibitor, in contrast to typical Pt formulations, and so questions arose about how fast the catalyst could trigger curing if it were used in a more activated form. Studies on the activation of RhCl3(Bu2S)3 revealed multiple intermediates, of which [RhCl(Bu2S)2]2 and [RhHCl(SiMe(OSiMe3)2) (Bu2S)2]2 were isolated. [RhHCl(SiMe(OSiMe3)2)(Bu2S)2]2 is the most activated form of the precatalyst, showing a brief induction period. Various experiments were performed to analyze the nature of the catalyst, including Hg poisoning, addition of poison ligands, and comparisons versus Rh nanoparticles. The data tend to be more consistent with a molecular catalyst than Rh nanoparticles. Data are also provided that support the active catalyst containing a RhxClx(Bu2S)2x fragment, although the exact identity of the active catalyst is not yet determined.
