55446-31-6Relevant academic research and scientific papers
Trifluoromethylthio and trifluoromethylseleno derivatives of germane and digermane
Holmes-Smith, Rupert D.,Stobart, Stephen R.
, p. 538 - 543 (1979)
Reactions of halogenogermanes with Hg(ECF3)2 (E = S or Se) provide a route to the compounds GeH3ECF3 and GeH2(ECF3)2. The latter in particular exhibit unusual thermal stability in comparison with related derivatives, as do the digermanes Ge2H5ECF3 prepared by reaction of the mercury(II) salts in diethyl ether with digermanyl iodide in situ at -63°C. IR, Raman, mass spectrometric, and 1H and 19F NMR data are reported and discussed for the new compounds.
