55470-90-1Relevant articles and documents
Triamidotoluene nucleating agent, preparation method and method of use
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, (2022/01/10)
The present invention provides a triamidotoluene nucleating agent, preparation method and method of use. Among them, triamidotoluene nucleating agent, is an N,N,N-triacyl-2,4,6-triaminotoluene compound, which can be used as a nucleating agent for polymer
A novel kind of configurational dissymmetry. Preparation, resolution, and circular dichroism of cis-bis(1(a)-methyl-2(a),4(a),6(a)-triaminocyclohexane)cobalt(III) ion
Freeman, Wade A.,Liu, Chui Fan
, p. 2120 - 2124 (2007/10/16)
The ligand 1-methyl-2,4,6-triaminocyclohexane (Metach) has been prepared by a two-step catalytic reduction of 2,4,6-trinitrotoluene. The isomer isolated has all equatorial substituents on the cyclohexane ring. The bis cobalt(III) complex has been prepared and resolved with d-bromocamphorsulfonate. The visible-ultraviolet circular dichroism spectrum of the resolved ion has a single gaussian extremum of low magnitude. The enantiomer isolated is tentatively assigned the Λ absolute configuration on the basis of sector rule arguments.