55546-42-4Relevant academic research and scientific papers
Epoxide hydrolysis and alcoholysis reactions over crystalline Mo-V-O oxide
Zhang, Xiaochen,Wang, Min,Zhang, Chaofeng,Lu, Jianmin,Wang, Yehong,Wang, Feng
, p. 70842 - 70847 (2016)
Crystalline Mo-V-O oxides have been used as a catalyst for the hydrolysis and alcoholysis of propylene oxide to diols and ethers, respectively. Relationships between the active crystal facet, the acidity of Mo-V-O catalysts and the activity have been established. Our results indicate that the a-b plane is the active facet for the hydrolysis reaction.
The Use of Proton-exchanged X-Type Zeolite in Catalysing Ring-opening Reactions of 2-Substituted Epoxides with Nucleophiles and its Effect on Regioselectivity
Takeuchi, Hiroshi,Kitajima, Kunio,Yamamoto, Yasuhiro,Mizuno, Kiyokazu
, p. 199 - 203 (2007/10/02)
The use of proton-exchanged X-type zeolite in catalysing ring-opening reactions of 2-alkyl substituted epoxides with nucleophiles gives a high regioselectivity and functional-selective catalysis giving allylic products from allylic nucleophiles.Mechanistic aspects are discussed.
