556068-55-4Relevant academic research and scientific papers
Determination of the absolute stereochemistry of Etzionin
Vaz, Esther,Fernandez-Suarez, Miryam,Munoz, Luis
, p. 1935 - 1942 (2003)
The absolute configuration of Etzionin, a marine peptide-like compound isolated in 1989 from a red tunicate collected from the Red Sea has been determined by a combination of synthetic and spectroscopic procedures. Finally, its absolute stereochemistry ha
A new asymmetric synthesis of 2,6-cis-disubstituted 4-methylenepiperidines: Total synthesis of (+)-alkaloid 241D and (+)-isosolenopsin A
Monfray, Jeremy,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
, p. 1025 - 1034 (2007/10/03)
A highly diastereoselective synthesis of 2,6-cis-disubstituted-4- methylenepiperidines based on a Mannich type intramolecular cyclization of an allylsilane on an iminium ion is described. The synthetic potential of this methodology is demonstrated by the
A facile enantioselective synthesis of 2-(2-aminoethyl)allylsilanes, new synthons for piperidine synthesis
Monfray, Jérémy,Gelas-Mialhe, Yvonne,Gramain, Jean-Claude,Remuson, Roland
, p. 5785 - 5787 (2007/10/03)
The synthesis of chiral (2-substituted-2-aminoethyl)allylsilanes by cerium mediated trimethylsilylmethylmagnesium chloride addition to the ester group of non racemic chiral β-aminoesters is described.
