55629-31-7Relevant academic research and scientific papers
A synthesis of di- and tri-substituted β,γ-unsaturated esters from aldehydes by the magnesium carbenoid 1,2-CH and 1,2-CC insertion as the key reaction
Yamashita, Hironori,Satoh, Tsuyoshi
experimental part, p. 613 - 627 (2009/04/06)
Addition reaction of 1-chlorovinyl p-tolyl sulfoxides, which were derived from aldehydes, with lithium enolate of tert-butyl acetate at -78 °C in THF gave adducts in high yields. Treatment of these adducts with Grignard reagents resulted in the formation
A new synthesis of β,γ-unsaturated esters from three components, aldehydes, chloromethyl p-tolyl sulfoxide, and tert-butyl acetate, via magnesium carbenoid 1,2-CH and 1,2-CC insertion as the key reaction
Satoh, Tsuyoshi,Yamashita, Hironori,Musashi, Jun
, p. 7295 - 7300 (2008/03/13)
Addition reaction of 1-chlorovinyl p-tolyl sulfoxides, which were derived from various aldehydes, with lithium enolate of tert-butyl acetate at -78 °C in THF gave adducts in high yields. Magnesium carbenoids were generated by treatment of these adducts wi
