55649-03-1Relevant academic research and scientific papers
Preparation and Characterization of the Uranyl Fluoride-Antimony Pentafluoride Adduct, UF2O2*4SbF5
Holloway, John H.,Laycock, David,Bougon, Roland
, p. 1635 - 1636 (1982)
When UF4O*2SbF5 is treated with anhydrous hydrogen fluoride a slow reaction in solution takes place.Investigation of this reaction and those of UF4O-SbF5-HF solutions on standing have shown that, in both cases, UF6 and a new uranyl fluoride derivative, UF2O2*4SbF5, are produced.
Crystal structures of phases observed in [H3O]+/M2+/[SbF6]?system (M?=?Mg, Cr, Mn, Fe, Co, Ni, Cu, Zn, Pd, Cd)
Mazej, Zoran,Goreshnik, Evgeny
, p. 82 - 88 (2017)
The reactions between the MO (M?=?Be, Mg, Ca, Sr, Ti, V, Nb, Mn, Ni, Cu, Pd, Zn, Hg, Sn, Pb) and SbF5in liquid aHF were investigated. Reactions with the MO (M?=?Mg, Ni, Cu and Zn) yielded H3OM(SbF6)3compounds. Both BeO and PdO didn't show any sign of reactivity meanwhile MO (M?=?V, Nb, Ti) gave products with M in oxidation state higher than two. The rest of the MO (M?=?Ca, Sr, Mn, Hg, Sn, Pb) formed mixtures of M(SbF6)2, H3OSbF6and/or H3OSb2F11. Reactions between H3OSbF6and M(SbF6)2(M?=?Fe, Co, Ni) also gave H3OM(SbF6)3compounds, meanwhile similar attempts with H3OSbF6and M(SbF6)2(M?=?Ca, Mn, Pd, Ag, Cd, Sn) to prepare [H3O]+/M2+/[SbF6]?salts failled. However, slow crystallizations of H3OSbF6and M(SbF6)2(M?=?Mn, Pd, Cd) mixtures resulted in the single crystal growth of new (H3O)3M(SbF6)5phases which crystal structures are not isotypic. Similar procedure with H3OSbF6/Cr(SbF6)2mixture resulted in few light orange crystals of (H3O)3[CrIV(SbF6)6](Sb2F11)·HF. Its crystal structure determination showed the presence of discrete [CrIV(SbF6)6]2?units where each of Cr atoms is found in a homoleptic coordination of six SbF6groups.
The [NH3Cl]+ ion
Schneider, Stefan,Haiges, Ralf,Schroer, Thorsten,Boatz, Jerry,Christe, Karl O.
, p. 5213 - 5217 (2007/10/03)
Stable! The first stable salts containing a simple, inorganic cation with an N-Cl bond are prepared (see picture). They are [NH3Cl] +[BF4]-, [NH3Cl] +[AsF6]-, and [NH3Cl] +[SbF6]- and can be safely prepared from (Me3Si)2NCl in mixtures of HF and the corresponding Lewis acids and could be used as storable generators for monochloramine gas.
