55659-53-5

Upstream product

• 158852-31-4 3,4,6-tri-O-benzyl-1,2-O-(exo-ethoxyethylidene)-α-D-glucopyranose 
• 65827-55-6 1,2-di-O-acetyl-3,4,6-tri-O-benzyl-α-D-glucopyranoside 
• 38081-38-8 3,4,6-tri-O-acetyl-1,2-O-<1-(exo-ethoxy)ethylidene>-α-D-glucopyranose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 108869-64-3 3,4,6-tri-O-benzyl-2-O-acetyl-α-D-glucosyl trichloroimidate 
• 677766-64-2 S-ethyl-2-O-acetyl-3,4,6-tri-O-benzyl-1-thio-α-D-glucopyranoside 
• 79218-68-1 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucopyranose 

Downstream Products

• 53929-30-9 benzyl 3,4,6-tetra-O-benzyl-β-G-glucopyranoside 
• 80738-62-1 2-O-acetyl-3,4,6-tri-O-benzyl-1,5-anhydro-D-arabino-hex-1-enitol 
• 455928-97-9 methyl 3,4,6-tri-O-benzyl-1-thio-β-D-glucopyranoside 
• 98906-49-1 methyl 3,4,6-tri-O-benzyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 
• 88087-47-2 O-(2,3,4,6-tetra-O-acetyl-α-D-mannopyranosyl)-(1->2)-O-(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2-acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-β-D-glucopyranose 
• 88087-44-9 2-acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-4-O-(3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-β-D-glucopyranose 
• 88087-45-0 2-acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-4-O-(3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-β-D-glucopyranose 
• 88087-46-1 2-acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-mannopyranosyl)-β-D-glucopyranose 
• 1381861-51-3 C₅₈H₅₆N₂O₁₁ 
• 214131-55-2 benzyl O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-(1-3)-O-(2-deoxy-4,6-O-isopropylidene-2-phthalimido-β-D-glucopyranosyl)-(1-4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 214467-66-0 Acetic acid (2S,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-[(2R,3S,4R,5R,6S)-4-benzyloxy-2-benzyloxymethyl-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-6-ethylsulfanyl-tetrahydro-pyran-3-yloxy]-6-benzyloxymethyl-tetrahydro-pyran-3-yl ester 
• 88087-43-8 2-acetamido-1,6-anhydro-3-O-benzyl-2-deoxy-4-O-(2-O-acetyl-3,4,6-tri-O-benzyl-β-D-glucopyranosyl)-β-D-glucopyranose 
• 99050-03-0 3,4,6-Tri-O-benzyl-1,2-O-<(2E,4S,6R,7E,11E)-1-(4-hydroxycembra-2,7,11-trien-6-yloxy)ethyliden>-α-D-glucopyranose 
• 136597-27-8 methyl-2-O-benzyl -3-O-(2-O-acetyl-3,4,6-tri-O-benzyl-α-D-mannopyranosyl)-4,6-O-benzylidene-α-D-glucopyranoside 

Relevant academic research and scientific papers

D-Glucose and d-mannose-based metabolic probes. Part 3: Synthesis of specifically deuterated d-glucose, d-mannose, and 2-deoxy-d-glucose

Altered carbohydrate metabolism in cancer cells was first noted by Otto Warburg more than 80 years ago. Upregulation of genes controlling the glycolytic pathway under normoxia, known as the Warburg effect, clearly differentiates malignant from non-maligna

Total Synthesis of Quercetin 3-Sophorotrioside

5,7-Dihydroxy-3-[β-D-glucopyranosyl-(1→2)-β -D-glucopyranosyl-(1→2)-β-D-glucopyranosyl]-2-(3,4-dihydroxyphenyl) -4H-1-benzopyran-4-one (quercetin 3-sophorotrioside), a flavonol triglycoside, isolated from Pisum sativum shoots and showing protective effect

Syntheses of O-β-D-mannosyl-(1 → 4)-O-α-D-mannosyl-(1 → 3)-L-rhamnose and O-(2-acetamido-2-deoxy-β-D-mannosyl)-(1 → 4)-O-α-D-galactosyl-(1 → 4)-D-galactose via in-situ-activating glycosylation using 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucose

O-β-D-Mannopyranosyl-(1 → 4)-O-α-D-mannopyranosyl-(1 → 3)-L-rhamnopyranose, a trisaccharide including a repeating unit of the O-specific polysaccharide (OSP) of Bulkholderia vietnamiensis strain LMG 6988, and O-(2-acetamido-2-deoxy-β-D-mannopyranosyl)-(1 → 4)-O-α-D-galactopyranosyl-(1 → 4)-D-galactopyranose, a trisaccharide including a repeating unit of OSP of Acinetobactor baumannii serogroup O18, were synthesized by means of in-situ-activating glycosylation using 2-O-acetyl-3,4,6-tri-O-benzyl-D-glucopyranose (2ATBG) and a reagent mixture of p-nitrobenzenesulfonyl chloride, silver triflate, and 1,8-diazabicyclo[5.4.0]undec-7-ene, and related systems. New syntheses of 2ATBG, allyl 2,3,6-tri-O-benzyl-α-D-galactopyranoside, benzyl 2,3,6-tri-O-benzyl-α-D-galactopyranoside, and 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-mannopyranose are described.

An efficient one step dihydroxylation of 1,2-glycals with oxone in acetone

A number of glycals have been converted into the corresponding 1,2-diols in fair to good yields. The reaction appears to proceed via the corresponding epoxide which opens in situ.

Stereoselective 1,2-cis glycosylation of 2-O-Allyl protected thioglycosides

The technique of intramolecular aglycon delivery (IAD), whereby a glycosyl acceptor is temporarily appended to a hydroxyl group of a glycosyl donor is an attractive method that can allow the synthesis of 1,2-cis glycosides in an entirely stereoselective f

3,4,6-Tri-O-benzyl-α-D-arabino-hexopyranos-2-ulosyl Bromide: A Versatile Glycosyl Donor for the Efficient Generation of β-D-Mannopyranosidic Linkages

An expedient four-step sequence is described for the conversion of acetobromoglucose into the title 2-oxohexosyl ("ulosyl") bromide 4.Due to its O-benzyl protection, 4 is considerably more reactive than its acylated analogs 1-3: Ag2CO3-promoted glycosidat