556797-99-0Relevant academic research and scientific papers
SPANphos: A C2-symmetric trans-coordinating diphosphane ligand
Freixa, Zoraida,Beentjes, Mark S.,Batema, Guido D.,Dieleman, Cedric B.,Van Strijdonck, Gino P. F.,Reek, Joost N. H.,Kamer, Paul C. J.,Fraanje, Jan,Goubitz, Kees,Van Leeuwen, Piet W. N. M.
, p. 1284 - 1287 (2007/10/03)
Exclusively trans coordination is exhibited by SPANphos, a C2-symmetric diphosphane ligand containing a spiro center, which can be easily synthesized in three steps from cheap reagents. The crystal structures of the ligand and of the complex [P
