556814-88-1

Basic information

• Product Name: methyl 2,3-di-O-acetyl-4-O-[2,3,4,6-tetrakis-O-(4-bromobenzoyl)-β-D-glucopyranosyl]-β-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-acetyl-4-O-[2,3,4,6-tetrakis-O-(4-bromobenzoyl)-β-D-glucopyranosyl]-β-D-glucopyranoside
• CAS NO: 556814-88-1
• Molecular Weight: 1172.42
• Mol File: 556814-88-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-acetyl-4-O-[2,3,4,6-tetrakis-O-(4-bromobenzoyl)-β-D-glucopyranosyl]-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-acetyl-4-O-[2,3,4,6-tetrakis-O-(4-bromobenzoyl)-β-D-glucopyranosyl]-β-D-glucopyranoside(556814-88-1)
• EPA Substance Registry System: methyl 2,3-di-O-acetyl-4-O-[2,3,4,6-tetrakis-O-(4-bromobenzoyl)-β-D-glucopyranosyl]-β-D-glucopyranoside(556814-88-1)

Safety Data

• Hazardous Substances Data: 556814-88-1(Hazardous Substances Data)

Upstream product

• 162426-12-2 methyl 2,3-di-O-acetyl-4,6-di-O-benzylidene-β-D-glucopyranoside 
• 71117-37-8 (2R,4aR,6R,7R,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 709-50-2 methyl beta-D-glucopyranoside 
• 162284-49-3 methyl 2,3-di-O-acetyl-6-O-benzyl-β-D-glucopyranoside 
• 556814-87-0 methyl 4-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3-di-O-acetyl-6-O-benzyl-β-D-glucopyranoside 

Downstream Products

• 556814-91-6 methyl 4-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,6-tri-O-acetyl-α-D-glucopyranoside 
• 556814-89-2 methyl 4-O-(2,3,4,6-tetrakis-O-(p-bromobenzoyl)-β-D-glucopyranosyl)-2,3,6-tri-O-acetyl-β-D-glucopyranoside 

Relevant articles and documents

Ferric chloride: A mild and versatile reagent for the formation of 1,6-anhydro glucopyranoses

A novel method for the preparation of 1,6-anhydro glucopyranoses (mono- and disaccharides) utilizing anhydrous FeCl3 as Lewis acid is described. Treatment of methyl 6-O-benzyl and 6-O-p-methoxybenzyl-α/β D-glucopyranosides derivatives with FeCl3 in CH2Cl2 at room temperature and 40°C afforded 1,6-anhydro glucopyranosides in moderate to good yields, through a debenzylation and intramolecular glycosidation in one step. A plausible reaction pathway is proposed.