55693-21-5Relevant academic research and scientific papers
Factors affecting reactions of trialkylcyanoborates with imidoyl chlorides/trifluoroacetic anhydride
Jones, Dyfyr Heulyn,Smith, Keith,Elliott, Mark C.,El-Hiti, Gamal A.
, p. 6285 - 6289 (2015)
Abstract Methods for generating tert-alkyl organoboron species are in high demand as they are invaluable intermediates for the synthesis of quaternary carbon centres. Herein we report investigations into generation of tert-alkyl organoboron species using imidoyl chlorides as reagents in the organoboron cyanidation reaction. Although alkenyl side-products predominate in particularly hindered cases, tert-alkyl organoboron species can be successfully generated for less hindered examples.
