557-95-9Relevant academic research and scientific papers
Tandem synthesis of aromatic amides from styrenes in water
Sathe, Pratima A.,Karpe, Aniket S.,Parab, Aniket A.,Parade, Babasao S.,Vadagaonkar, Kamlesh S.,Chaskar, Atul C.
supporting information, p. 2820 - 2823 (2018/06/25)
An expedient one-pot synthesis of aromatic amides has been reported from styrenes in the presence of N-bromosuccinimide and iodine by using aqueous ammonia in water. The reaction proceeds through the formation of α-bromoketone as an intermediate in the pr
Applications of Phase Transfer Catalysis, 23. Note on Bromoiodocarbene and on Pertinent Halogen Exchange Processes
Dehmlow, Eckehard V.,Broda, Witold
, p. 3894 - 3897 (2007/10/02)
A rapid halogen exchange between HCBr3, HCBr2I, HCBrI2, and HCI3 occurred in the presence of conc. sodium hydroxide and a quaternary ammonium salt.Trapping experiments with various alkenes gave cyclopropane derivatives only in 3 cases.Depending on the nucleophilicity of the alkene and the haloform, different proportions of CBr2, CBrI, and CI2 adducts were obtained.The most nucleophilic acceptor trapped those carbenes preferentially that were formed by elimination of iodide.
