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2-Methyl-1-phenylazetidine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

55702-57-3

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55702-57-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 55702-57-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,5,7,0 and 2 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 55702-57:
(7*5)+(6*5)+(5*7)+(4*0)+(3*2)+(2*5)+(1*7)=123
123 % 10 = 3
So 55702-57-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H13N/c1-9-7-8-11(9)10-5-3-2-4-6-10/h2-6,9H,7-8H2,1H3

55702-57-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-methyl-1-phenylazetidine

1.2 Other means of identification

Product number -
Other names Azetidine,2-methyl-1-phenyl

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:55702-57-3 SDS

55702-57-3Downstream Products

55702-57-3Relevant academic research and scientific papers

4,4'-Di-tert-butylbiphenyl-Catalysed Reductive Opening of Azetidines with Lithium: A Direct Preparation of 3,N-Dilithioalkylamines

Almena, Juan,Foubelo, Francisco,Yus, Miguel

, p. 5775 - 5782 (2007/10/02)

The reaction of N-phenylazetidine 1a with an excess of lithium powder and a catalytic amount of 4,4'-di-tert-butylbiphenyl (5 molpercent) in THF at -15 deg C leads to the corresponding dianion 2a, which by treatment with different electrophiles (H2O, D2O, ButCHO, PhCHO, (CH2)5CO, PhCH=NPh, CO2) yields, after hydrolysis with water, the expected functionalysed amines 3aa-ah.The same method applied to N-isopropyl-2-phenylazetidine 1c affords compounds 3ca-ce (electrophiles: H2O, D2O, PhCHO, Me2CO, CH2=CHCH2Br) resulting from the more stable benzylic intermediate 2c.Finally, the regiochemistry in the reductive opening of 2-methyl-N-phenylazetidine 1d followed by deuterolysis was studied: a mixture of both regioisomers 3da+3da' was obtained, the ratio being the oposite as expected according to the stability of both intermediates 2d and 2d'.

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