55712-53-3Relevant academic research and scientific papers
Efficient Homocoupling of Aryl- and Alkenylboronic Acids in the Presence of Low Loadings of [{Pd(μ-OH)Cl(IPr)} 2 ]
Ostrowska, Sylwia,Rogalski, Szymon,Lorkowski, Jan,Walkowiak, Jedrzej,Pietraszuk, Cezary
supporting information, p. 1735 - 1740 (2018/07/21)
NHC-palladium(II) complex [{Pd(μ-OH)Cl(IPr)} 2 ] (IPr = bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) catalyzes the oxidative coupling of a broad spectrum of aryl- and alkenylboronic acids at loadings down to 5 ppm. At the concentration of 0.05 mol% the catalyst permits an efficient reaction under base-free conditions.
