55821-21-1Relevant articles and documents
Quenched skeletal Ni as the effective catalyst for selective partial hydrogenation of polycyclic aromatic hydrocarbons
Liu, Chengyun,Rong, Zeming,Sun, Zhuohua,Wang, Yong,Du, Wenqiang,Wang, Yue,Lu, Lianhai
, p. 23984 - 23988 (2013/11/19)
Quenched skeletal Ni is an active and selective catalyst for selective partial hydrogenation of polycyclic aromatic hydrocarbons (PAHs). The molecular structure of PAHs significantly dominate the hydrogenation process and furthermore, the distribution of hydrogenated products.
Hydrogenation of pyrene using Pd catalysts supported on tungstated metal oxides
Lin, Qiang,Shimizu, Ken-Ichi,Satsuma, Atsushi
experimental part, p. 166 - 172 (2011/06/21)
A series of Pd catalyst supported on tungstated metal oxides (Pd/W-MOx) were prepared and applied for pyrene hydrogenation, and the role of acid sites of supports was investigated. Among Pd/W-MOx catalysts, Pd/W-TiO2 showed the highest activity which was comparable to those of Pd/BEA, Pd/Y and Pd/SiO2-Al2O3. As for the Pd catalysts supported on metal oxides without tungstate (Pd/MOx), the hydrogenation activity became higher with the increase in the acid amount of supports measured by calorimetric measurement of ammonia adsorption. The important role of acid sites on hydrogenation activity was demonstrated. On the other hand, the hydrogenation activity of Pd/W-MOx catalysts was not correlated to the acid amount of supports measured by ammonia adsorption. On-site generation of protonic acid on tungstated metal oxide supports was estimated from kinetic analysis of reduced W species in the presence of hydrogen by in situ UV-visible measurement. From a good correlation between the kinetic parameters of on-site protonic acid formation and the hydrogenation activity, the important role of protonic acid formation on tungstated metal oxide supports was clarified.
Hydropyrenes, Alicyclic Model Compounds for GC-MS Investigations
Mann, G.,Sicker, A.,Herzschuh, R.,Engewald, W.,Praefcke, K.
, p. 267 - 272 (2007/10/02)
Hydrogenation of asymmetric and symmetric hexahydropyrene gives the five possible aromatic decahydropyrenes via different octahydropyrenes.From these compounds some dodecahydro- and tetradecahydro-pyrenes, the four isomers of perhydropyrene with chair conformations and five new stereoisomers with twist boat six-membered rings are obtained.The configurations of the hydrogenated pyrenes are assigned using chromatographic retention indices and mass spectrometric fragmentation in combination with force field calculations.