55843-71-5Relevant articles and documents
ORGANIC TELLURIUM COMPOUND, METHOD FOR PRODUCING SAME, LIVING RADICAL POLYMERIZATION INITIATOR, METHOD FOR PRODUCING VINYL POLYMER, AND VINYL POLYMER
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Paragraph 0178-0181, (2020/02/27)
An organic tellurium compound is disclosed having a versatility that, when used as a living radical polymerization initiator, it is applicable to polymerization of a vinyl monomer in an aqueous vehicle without using any surfactant or dispersant. The organ
Formation of α-chalcogenyl acrylamides through unprecedented chalcogen-mediated metal-free oxyfunctionalization of ynamides with DMSO as an oxidant
Huang, Hai,Tang, Luning,Liu, Qi,Xi, Yang,He, Guangke,Zhu, Hongjun
supporting information, p. 5605 - 5608 (2016/05/09)
A novel chalcogen-mediated oxyfunctionalization mode of ynamides for the synthesis of α-chalcogenyl acrylamides has been developed. Independent of metal catalysts, external oxidants and additives, this mild process afforded a range of structurally diverse
Role of anagostic interactions in cycloplatination of telluroethers: Synthesis and structural characterization
Kolay, Siddhartha,Kumar, Mukesh,Wadawale, Amey,Das, Dasarathi,Jain, Vimal K.
, p. 40 - 47 (2015/07/08)
Abstract Reactions of K2PtCl4 with TeRRE′ gave complexes of composition [PtCl2(TeRRE′)2] (R/RE′ = Ph2(1a), o-tol2 (1b), Mes2(1c), Ph/Mes (1d), o-tol/Mes (1e)). The complex [PtCl2(TeMes2)2] in refluxing THF afforded a mononuclear cyclometalated complex [PtCl{(CH2C6H2Me2-4,6)TeMes}(TeMes2)] (2). It tends to remain in equilibrium with a binuclear derivative [Pt(μ-Cl){(CH2C6H2Me2-4,6)TeMes}]2 (3) in CDCl3 solution. The complexes 1d and 1e did not undergo cyclometalation reaction under similar reaction conditions. The 2 on treatment with PPh3 gave [PtCl{(CH2C6H2Me2-4,6)TeMes}(PPh3)] (4). All the complexes have been characterized by elemental analysis and NMR (1H, 31P, 125Te, 195Pt) spectroscopy. Anagostic interactions have been recognised for facilitation of cyclometalation reactions. The molecular structures of trans-[PtCl2(TeMes2)2] (1c), trans-[PtCl2(PhTeMes)2] (1d), trans-[PtCl2(o-tolTeMes)2] (1e), [PtCl{(CH2C6H2Me2-4,6)TeMes}(TeMes2)] (2) and [PtCl{(CH2C6H2Me2-4,6)TeMes}(PPh3)] (4) have been established unambiguously by single crystal X-ray diffraction analyses.