558484-57-4Relevant academic research and scientific papers
Allylboration of nitrosobenzene
Bubnov, Yurii N.,Pershin, Dmitrii G.,Karionova, Anna L.,Gurskii, Mikhail E.
, p. 202 - 203 (2007/10/03)
The allylboration of nitrosobenzene at -70°C resulted in the formation of N- and O-allyl derivatives of N-phenylhydrazine, which were reduced with the second allylborane molecule to N-allylaniline above 100°C.
Reductive reactions of nitroarenes in the presence of allyl bromide and zinc dust
Kim, Byeong Hyo,Kim, Tae Kyu,Cheong, Jae Wook,Lee, Sang Woo,Jun, Young Moo,Baik, Woonphil,Lee, Byung Min
, p. 1921 - 1928 (2007/10/03)
Under the mild condition, allyl bromide/Zn mediated reductive N,O- diallylation of nitrobenzene was observed. In case of o-nitroarenes such as 2-nitrobenzaldehyde derivatives, 2'-nitroacetophenone, and N-(2- nitrobenzylidene)anilines, reductive cyclizations were accomplished in good to excellent yields. Synthesis and mechanistic details are discussed.
