55866-28-9Relevant articles and documents
24,24-DIMETHYL-25-DEHYDROLOPHENOL, A 4α-METHYLSTEROL FROM CLERODENDRUM INERME
Akihisa, Toshihiro,Ghosh, Parthasarathi,Thakur, Swapnadip,Nagata, Hiroshi,Tamura, Toshitake,Matsumoto, Taro
, p. 1639 - 1641 (1990)
The structure of a new 4α-methylsterol isolated from aerial parts of Clerodendrum inerme has been shown to be 4α,24,24-trimethyl-5α-cholesta-7,25-dien-3β-ol (24,24-dimethyl-25-dehydrolophenol) based mainly on the 1H NMR spectroscopic comparison with known compounds.In addition 24β-ethyl-25-dehydrolophenol and two other common 4α-methylstyrols were isolated and identified.
4α,14α-DIMETHYL-5α-ERGOSTA-7,9(11),24(28)-TRIEN-3β-OL FROM PHASEOLUS VULGARIS AND GYNOSTEMMA PENTAPHYLLUM
Akihisa, Toshihiro,Kokke, W. C. M. C.,Yokota, Takao,Tamura, Toshitake,Matsumoto, Taro
, p. 1647 - 1651 (1990)
The structure of a new 4α-methylsterol isolated from the immature seeds of Phaseolus vulgaris and the aerial parts of Gynostemma pentaphyllum has been shown to be 4α,14α-dimethyl-5α-ergosta-7,9(11),24(28)-trien-3β-ol by spectroscopic methods and by chemical correlation with obtusifoliol.This appears to be the first report of the isolation of a 4α-methylsterol with a Δ7,9(11)-diene system from nature.Abundances and chromatographic data of all identified 4α-methylsterols isolated from G. pentaphyllum are also given.