55916-43-3

Upstream product

• 91589-00-3 Dichlor-benzylmercapto-phosphin 
• 100-53-8 phenylmethanethiol 

Downstream Products

• 68904-95-0 C₂₁H₁₇F₆N₂PS₂ 
• 68904-93-8 C₁₉H₁₅Cl₄N₂PS₂ 
• 130659-74-4 C₅₀H₅₃N₄O₁₃PS₂ 
• 130659-73-3 Dithiophosphoric acid O-benzotriazol-1-yl ester S-benzyl ester O'-[(2R,3S,5R)-2-[bis-(4-methoxy-phenyl)-phenyl-methoxymethyl]-5-(5-methyl-2,4-dioxo-3,4-dihydro-2H-pyrimidin-1-yl)-tetrahydro-furan-3-yl] ester 
• 130659-71-1 Dithiophosphoric acid O,O'-dibenzotriazol-1-yl ester S-benzyl ester 

Relevant academic research and scientific papers

Process for preparing mono- and disubstituted mercapto-phosphorothionochloridates

Mono- and disubstituted mercaptophosphorothionochloridates are prepared by reacting a disubstituted sulfide having the formula wherein each R is an independently selected alkyl, cycloalkyl or benzyl, with phosphorus pentasulfide and thiophosphorus trichloride at a temperature from about 150° to about 300° C. A molar ratio of R2 S to P4 S10 to P(S)Cl3 of 6:1:8 is preferred where the monosubstituted compound is desired, while a ratio of 6:1:2 is preferred where the disubstituted compound is desired. The compounds are useful as intermediates for compounds which exhibit biocidal properties, particularly insecticides and herbicides.