5596-21-4

Usage

Uses

Used in Pharmaceutical Industry:
Methyl 2-O-[(4-methylphenyl)sulfonyl]hexopyranoside serves as a valuable building block for the synthesis of a wide range of glycosides and related compounds. Its unique chemical structure allows for the development of new pharmaceutical agents with potential therapeutic benefits.
Used in Chemical Industry:
In the chemical industry, methyl 2-O-[(4-methylphenyl)sulfonyl]hexopyranoside can be utilized in the creation of various chemical products, taking advantage of its sulfonyl group and hexopyranoside backbone for specific chemical reactions and processes.
Further research is necessary to fully explore and understand the potential of methyl 2-O-[(4-methylphenyl)sulfonyl]hexopyranoside, enabling its effective use in both the pharmaceutical and chemical industries.

Upstream product

• 98-59-9 p-toluenesulfonyl chloride 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 70774-92-4 methyl 4,6-O-benzylidene-2-O-p-toluenesulphonyl-α-D-glucopyranoside 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 4124-41-8 p-toluenesulfonylanhydride 

Downstream Products

• 52482-80-1 methyl 2-deoxy-2-C-(hydroxymethyl)-α-D-ribo-pentofuranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 34327-07-6 3,4,6-tri-O-methyl-D-glucose 

Relevant academic research and scientific papers

Chemo- and regioselective monosulfonylation of nonprotected carbohydrates catalyzed by organotin dichloride under mild conditions

The catalytic regioselective monosulfonylation of nonprotected carbohydrates using organotin dichloride under mild conditions is examined. The carbohydrates were chemo- and regioselectively converted to the corresponding monosulfonates in the presence of

Synthesis of Methyl 6-Deoxy-6-diphenylphosphino-α-D-glucopyranoside: Temperature-Dependence of the Primary O-Tosyl Cleavage Mode

Methyl α-D-glucopyranoside is converted to methyl 6-p-toluenesulfonyl-2,3,4-tris-O-trimethylsilyl-α-D-glucopyranoside 2 and then reacted with lithium diphenylphosphide in THF. When the reaction is carried out at room temperature and below, S-O cleavage dominates giving methyl 2,3,4-tris-O-trimethylsilyl-α-D-glucopyranoside 3, whereas at 60°C in THF or at 35°C in diethyl ether, C-O cleavage occurs yielding the title carbohydrate-phosphine 4 in good yield after deprotection.

Regioselective monotosylation of non-protected and partially protected glycosides by the dibutyltin oxide method

Tosylation of non-protected glycopyranosides with p-toluenesulfonyl chloride in the presence of 4-dimethylaminopyridine, after activiation of the glycosides by dibutyltin oxide, gave mono-O-tosylates in good yield. The regioselectivity in this tosylation

REGIOSELECTIVE STANNYLATION. ACYLATION OF CARBOHYDRATES: COORDINATION CONTROL

An efficient method for the regioselective enhancement of the nucleophilicity of polyhydroxy compounds has been developed.Partial stannylation of carbohydrate with (Bu3Sn)2O and subsequent electrophilic attack with benzoyl chloride gave rise to regioselec