55998-95-3Relevant articles and documents
Aldol Reaction of Aluminium Enolate Resulting from 1,4-Addition of R2AlX to α,β-Unsaturated Carbonyl Compound. A 1-Acylethenyl Anion Equivalent
Itoh, Akira,Ozawa, Shuji,Oshima, Koichiro,Nozaki, Hitosi
, p. 274 - 278 (2007/10/02)
Organoaluminium reagents R2AlX (X=SPh, SeMe) easily add to α,β-unsaturated carbonyl compounds in 1,4-fashion.The resulting aluminium enolates react with aldehydes to give aldol adducts in fair to good yields.Formal elimination of HX from the adducts provi