5603-16-7Relevant academic research and scientific papers
The synthesis and characterization of a series of bis-bidentate Schiff base ligands and their coordination complexes with silver(I), copper(I) and zinc(II) d10 metal ions
Patra, Goutam Kumar,Goldberg, Israel
, p. 1124 - 1131 (2003)
Three bis-bidentate Schiff base ligands 1, 2 and 3 have been prepared and thoroughly characterized, and their complexation behavior with d10 silver, copper and zinc ions was studied. The coordination assembly of Cu(I) and Ag(I) with ligands 1 a
Recognition of Hg2+ ion through restricted imine isomerization: Crystallographic evidence and imaging in live cells
Mandal, Amal Kumar,Suresh, Moorthy,Das, Priyadip,Suresh,Baidya, Mithu,Ghosh, Sudip K.,Das, Amitava
, p. 2980 - 2983 (2012)
A newly synthesized imine-based receptor (L) showed remarkable specificity toward the Hg2+ ion in aqueous media over other metal ions. Coordination of L to Hg2+ induces a turn-on fluorescence response. This was explained based on the restricted imine isomerization along with PET on coordination to Hg2+. X-ray structural evidence tends to favor a C-C bond rotation rather than C=N isomerization for adopting a favorable conformation in L for coordination to Hg2+. This reagent could be used for imaging the accumulation of Hg2+ ions in HeLa cells.
