56058-26-5Relevant academic research and scientific papers
Acid-Catalyzed Transformations of 1-Chloro-2-Nitrobenzylcyclopropanes. First Stable Ions of N-Oxo-2,1-benzooxazepinium
Mochalov,Trofimova,Fedotov,Shabarov,Zefirov
, p. 817 - 825 (2007/10/03)
Transformations of 1-chloro-2-(2-nitrobenzyl)- and 1-chloro-2-(4-nitrobenzyl)cyclopropanes under the action of sulfuric and fluorosulfonic acid are studied. Three-membered cycle of these compounds is opened presumably at the C1-C3 an
EFFICIENT METHOD FOR THE SYNTHESIS OF MONOHALOCYCLOPROPANES BY REDUCTION OF GEM-DIHALOCYCLOPROPANES BY REDUCTION OF GEM-DIHALOCYCLOPROPANES WITH i-Bu2AlH IN THE PRESENCE OF Ti AND Zr COMPLEXES
Dzhemilev, U. M.,Gaisin, R. L.,Turchin, A. A.,Khalikova, N. R.,Baikova, I. P.,Tolstikov, G. A.
, p. 967 - 974 (2007/10/02)
We have investigated the reductive dehalogenation reaction of alkyl and aryl substituted gem-dihalocyclopropanes with diisobutyl aluminum hydride in the presence of catalytic amounts of titanium and zirconium complexes.As a result we propose a general method for the synthesis of substituted monohalocyclopropanes and cyclopropanes of various structures.We have also studied the stereochemistry of the reduction.
