56222-36-7

Basic information

• Product Name: N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine
• Synonyms: N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine;(N,NE,N,NE)-N,N-(ETHANE-1,2-DIYLIDENE)BIS(2,4,6-TRIMETHYLANILINE);N,N'-(Ethane-1,2-diylidene)bis(2,4,6-trimethylaniline)
• CAS NO: 56222-36-7
• Molecular Formula: C₂₀H₂₄N₂
• Molecular Weight: 292.41796
• Mol File: 56222-36-7.mol
• Article Data: 45

Chemical Properties

• Melting Point: 157 °C
• Appearance: /
• CAS DataBase Reference: N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine(56222-36-7)
• EPA Substance Registry System: N,N'-bis(2,4,6-trimethylphenyl)ethane-1,2-diimine(56222-36-7)

Safety Data

• Hazardous Substances Data: 56222-36-7(Hazardous Substances Data)

Upstream product

• 131543-46-9 Glyoxal 
• 88-05-1 2,4,6-trimethylaniline 
• 1048658-22-5 1,4,6,9-tetramesityl-1,4,6,9-tetraaza-5-phosphoniaspiro[4.4]non-2-ene trifluoromethanesulfonate 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 
• 100054-69-1 4-isopropoxy-2,6-dimethylaniline 
• 67565-93-9 N-(diphenyl methylene)-2,4,6-trimethylaniline 
• 576-83-0 2,4,6-trimethylphenyl bromide 
• 4405-13-4 glyoxal trimer dihydrate 

Downstream Products

• 258278-23-8 N¹,N²-dimesitylethane-1,2-diaminium chloride 
• 306283-68-1 2,4-Dichloro-1,3-dimesityl-1,3,2-diazaphospholene 
• 306283-67-0 2-chloro-1,3-bis(2,4,6-trimethylphenyl)-1,3,2-diazaphosphalene 
• 141556-45-8 1,3-bis(mesityl)imidazolium chloride 
• 173035-10-4 1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazolium chloride 
• 173035-11-5 1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene 
• 258278-26-1 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene 
• 889454-13-1 (2,4,6-Me₃C₆H₂)NC(H)C(H)N(2,4,6-Me₃C₆H₂)AsSnCl₅*C₄H₈O 
• 1048658-20-3 1,4-dimesityl-6,9-di(4-methoxyphenyl)-1,4,6,9-tetraaza-5-phosphoniaspiro[4.4]non-2-ene trifluoromethanesulfonate 
• 1048658-18-9 1,4-dimesityl-6,9-diphenyl-1,4,6,9-tetraaza-5-phosphoniaspiro[4.4]non-2-ene trifluoromethanesulfonate 
• 1048658-22-5 1,4,6,9-tetramesityl-1,4,6,9-tetraaza-5-phosphoniaspiro[4.4]non-2-ene trifluoromethanesulfonate 
• 78199-26-5 Ru(CO)3(mesityl-N=CHCH=N-mesityl) 
• 263571-46-6 bis[N,N'-bis(2,4,6-trimethylphenyl)-1,2-ethanediylidenediamine]copper(I) tetrafluoroborate 
• 449775-22-8 ((CH₃)3C₆H₂NCH)2GaI₂ 

Relevant articles and documents

Synthesis of conjugated Mn porphyrin polymers with p-phenylenediamine building blocks and efficient aerobic catalytic oxidation of alcohols

A series of conjugated metalloporphyrin polymers (MnP-AMPs) were synthesized based on Buchwald-Hartwig aromatic amination with p-phenylenediamine and manganese tetraphenylporphyrin as building blocks, and N-heterocyclic carbene-palladium complex as cataly

Aluminum nanoparticle preparation: Via catalytic decomposition of alane adducts-influence of reaction parameters on nanoparticle size, morphology and reactivity

Al nanoparticles represent one of the most challenging classes of metal nanoparticles in synthesis and handling due to their high chemical reactivity and their affinity to oxidation. A promising wet chemical preparation route is the catalytic decomposition of alane adducts. In the current systematic study, we investigated the influence of various reaction parameters, such as precursors, catalysts, solvents, reaction temperatures, capping agents, and concentrations of the reactants on the size and morphology of the resulting Al nanoparticles. One major goal was the optimization of the reaction parameters towards short reaction times. Our studies revealed that Ti alkoxides, such as Ti(OiPr)4, are much more efficient decomposition catalysts compared to other related metal catalysts. Optimized conditions for full conversion times smaller than 15 min are temperatures between 90-100 °C and non-polar solvents such as toluene. Amine alanes containing short alkyl chains, for example H3AlNMe2Et or H3AlNEt3, were the most suitable precursors, leading to the formation of the smallest nanoparticles. The use of weakly coordinating capping agents like amines and phosphines should be preferred over the commonly employed carboxylic acids because they do not accelerate the formation of an amorphous oxide shell upon binding to the particle surface. In conclusion, the best reaction parameters for a fast synthesis of Al nanoparticles via a catalytic decomposition approach are the combination of sterically less hindered amine alanes applying a Ti catalyst in toluene solutions in the presence of amine or phosphine stabilizers at elevated temperatures.

Method for preparing substituted aryl ketone by ketone arylation (by machine translation)

The invention provides a method, for preparing substituted aryl ketone, by using a nitrogen heterocyclic carbene catalyst, with a saturated nitrogen heterocyclic carbene structure in an oxygen-containing atmosphere at, through α - catalysis of a nitrogen heterocyclic carbene structure, in a nitrogen heterocyclic carbene catalyst with a saturated nitrogen heterocyclic carbene structure under an alkaline condition, in an oxygen-containing atmosphere and can efficiently prepare various substituted, aryl ketones α - under the condition of containing an oxygen. atmosphere. (by machine translation)