56261-10-0

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 22031-12-5 [2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine] 

Downstream Products

• 89063-20-7 Pt(triphos)(P(mesityl)=CPh₂) 
• 134494-05-6 {Pt(1,1,1-tris(diphenylphosphinomethyl)ethane)(SPh)(H)} 
• 134494-04-5 {Pt(1,1,1-tris(diphenylphosphinomethyl)ethane)(SH)(H)} 

Relevant academic research and scientific papers

Synthesis and Dynamic Stereochemistry of the Complexes (SR)(H)> (R = H or Ph)

The cis square-planar hydrido mercapto derivatives and have been prepared by reaction of with H2S or HSPh.Analysis of the 1H and 31P NMR data for the two complexes over a temperature range encompassing slow- and fast-exchange limits characterizes these molecules as stereochemically nonrigid on the NMR time-scale.The fluxional behaviour can be explained on the basis of intramolecular exchange of the unco-ordinated phosphorus atom of triphos with the phosphorus atom co-ordinated in cis position to the hydride ligand.At higher temperature, a complete scrambling of the three phosphorus atoms occurs, and at the fast-exchange limit the spin correlation between the phosphorus atoms and platinum metal is retained.The related complexes (dppp = Ph2PCH2CH2CH2PPh2), and have been prepared in order to clarify the mechanism of the fluxionality for (R = H or Ph).