56345-78-9Relevant academic research and scientific papers
Convenient synthesis of aryl-substituted halo olefins from aromatic ketones and acetyl halides in the presence of silica gel-supported zinc halides
Kodomari, Mitsuo,Nagaoka, Takashi,Furusawa, Yuhsuke
, p. 3105 - 3107 (2007/10/03)
A simple and efficient procedure has been developed for the synthesis of aryl-substituted chloro and bromo olefins from aromatic ketones and acetyl halides in the presence of silica gel-supported zinc halides. The Z-isomer is selectively formed.
Alkenyl bromides by brominative deoxygenation of ketones in one or two steps
Von Roman,Ruhdorfer,Knorr
, p. 985 - 992 (2007/10/02)
The conversion of ketones into alkenyl bromides is accomplished in one or two steps by 2,2,2-tribromo-2,2-dihydro-1,3,2-benzodioxaphosphole or by the dibromomethyl methyl ether prepared therefrom. Investigations of the scope and limitations provide some hints for the preparative planning and improvement.
SYNTHESIS OF Z-1-BROMO-1-ALKENYLBENZENES
Oliva, Alfonso,Molinari, Aurora
, p. 837 - 842 (2007/10/02)
Z-1-Bromo-1-alkenylbenzenes are synthesized by bromination-desilicobromination of (E-1-phenyl-1-alkenyl)trimethylsilanes.
