56438-64-3

Upstream product

• 1798-09-0 m-methoxyphenylacetic acid 
• 63075-61-6 (3-methoxy-phenyl)-acetic acid-anhydride 
• 19924-43-7 3-methoxyphenylacetonitrile 
• 541-41-3 chloroformic acid ethyl ester 
• 824-98-6 m-methoxybenzyl chloride 
• 38622-91-2 [(p-methylphenyl)sulfonylmethyl]isonitrile 
• 6834-42-0 3-methoxyphenylacetic acid chloride 
• 4755-77-5 Ethyl oxalyl chloride 

Downstream Products

• 51053-85-1 3-methoxybenzyl radical 
• 1386995-35-2 2,5-bis-(3-methoxy-phenyl)-3,4-diphenyl-cyclopenta-2,4-dienone 
• 1408319-71-0 3,4-bis(4-butylphenyl)-2,5-bis(3-methoxyphenyl)cyclopenta-2,4-dienone 
• 1386995-37-4 (Z)-3-(3-methoxyphenyl)-2-((3-methoxyphenyl)(3-(3-methoxyphenyl)-4,5-diphenyl-2H-pyrrol-2-ylidene)methyl)-4,5-diphenyl-1H-pyrrole 
• 1408319-77-6 (Z)-2-((4,5-bis(4-butylphenyl)-3-(3-methoxyphenyl)-2H-pyrrol-2-ylidene)(3-methoxyphenyl)methyl)-4,5-bis(4-butylphenyl)-3-(3-methoxyphenyl)-1H-pyrrole 

Relevant academic research and scientific papers

Preparation method of 1,3-disubstituted alkyl phenylacetone

The invention relates to a preparation method of 1,3-disubstituted alkyl phenylacetone and belongs to the field of medical technology and photoelectric materials. The preparation method includes: allowing alkyl phenylacetic acid to have reaction with DMAP

Preparation method and application of 1,3-disubstituted alkyl phenyl acetone

The invention belongs to the field of pharmaceutical technology and photoelectric material and relates to a preparation method and application of 1,3-disubstituted alkyl phenyl acetone. The 1,3-disubstituted alkyl phenyl acetone is prepared by: dissolving

From Alkyl Halides to Ketones: Nickel-Catalyzed Reductive Carbonylation Utilizing Ethyl Chloroformate as the Carbonyl Source

Ketones are an important class of molecules in synthetic and medicinal chemistry. Rapid and modular synthesis of ketones remains in high demand. Described here is a nickel-catalyzed three-component reductive carbonylation method for the synthesis of dialkyl ketones. A wide range of both symmetric and asymmetric dialkyl ketones can be accessed from alkyl halides and a safe CO source, ethyl chloroformate. The approach offers complementary substrate scope to existing carbonylation methods while avoiding the use of either toxic CO or metal carbonyl reagents.

A novel synthesis of bisbenzyl ketones by DCC induced condensation of phenylacetlc acid

1,3-Dicyclohexylcarbodiimide (DCC) has been found to effect condensation of two molecules of phenylacetic acids in the presence of dimethylaminopyridine leading to the formation of bisbenzyl ketones.

ACTIVATED METALLIC NICKEL IN PREPARATION OF SYMMETRICAL 1,3-DIARYLPROPAN-2-ONES FROM BENZYLIC HALIDES AND OXALYL CHLORIDES

Oxidative addition of benzylic halides to nickel in the metallic state followed by insertion of carbon monoxide generated from alkyl oxalyl chlorides proceeded smoothly to give symmetrical 1,3-diarylpropan-2-ones in moderate yields.

Self-Termination and Electronic Spectra of Substituted Benzyl Radicals in Solution

Several substituted benzyl radicals have been generated in liquid cyclohexane by the photolysis of symmetrically substituted dibenzyl ketones.The rate constants for self-termination to substituted bibenzyls, and absorption spectra of the transient radicals, have been measured by optical modulation spectroscopy.The termination rates are generally well described by the von Smoluchowski equation with a spin factor of 1/4.Deviations are discussed in terms of steric retardation and the unreliability of the estimated reaction diameters of radicals with bulky substituent groups.Absorption spectra of the three monomethyl-, the three monochloro-, two dichloro-, and the three monomethoxybenzyl radicals demonstrate the influence of the substituents on the energy levels of the benzyl system.