564476-53-5

Upstream product

• 1067-71-6 Diethyl (2-oxopropyl)phosphonate 
• 564476-51-3 (1R,3S,5S)-3-(tert-butyl(dimethyl)silyloxy)-8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-one 
• 564476-63-7 (1S,3S,5S)-3-Hydroxy-8,8-dimethyl-2-methylene-6-oxa-bicyclo[3.2.1]octan-7-one 
• 564476-50-2 (1R,3R,5S)-3-hydroxy-8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-one 
• 564476-62-6 (1S,5S)-8,8-Dimethyl-2-methylene-6-oxa-bicyclo[3.2.1]octane-3,7-dione 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 358339-06-7 (1R,5S)-(+)-8,8-dimethyl-2-methylene-6-oxabicyclo[3.2.1]octan-7-one 

Downstream Products

• 564476-55-7 (1S,3R,5S)-5-tert-butyl(dimethyl)silyloxy-2,2-dimethyl-4-methylene-3-[(1'E)-3'-oxobut-1'-en-1'-yl]cyclohexyl acetate 
• 564476-57-9 (1S,3R,5S)-5-tert-butyl(dimethyl)silyloxy-2,2-dimethyl-3-[(3'R)-3'-hydroxy-3'methylpent-4'-en-1'-yl]-4-methylenecyclohexyl acetate 
• 564476-58-0 (1S,3R,5S)-5-tert-butyl(dimethyl)silyloxy-2,2-dimethyl-3-[(3'S)-3'-hydroxy-3'methylpent-4'-en-1'-yl]-4-methylenecyclohexyl acetate 
• 564476-56-8 (1S,3R,5S)-5-tert-butyl(dimethyl)silyloxy-2,2-dimethyl-4-methylene-3-(3'-oxobutyl)cyclohexyl acetate 
• 564476-61-5 (1S,3R,5S,3'R)-3-[3'-hydroxy-3'methylpent-4'-en-1'-yl]-5-methylsulfonyloxy-2,2-dimethyl-4-methylenecyclohexyl acetate 
• 173450-53-8 (1S,3R,5S,3'R)-3-[3'-hydroxy-3'methylpent-4'-en-1'-yl]-5-hydroxy-2,2-dimethyl-4-methylenecyclohexyl acetate 

Relevant academic research and scientific papers

First enantioselective synthesis and absolute stereochemistry assignment of new monocyclic sesquiterpenes from Artemisia chamaemelifolia

We herein report the first enantioselective synthesis of two new monocyclic sesquiterpenes from Artemisia chamaemelifolia starting from an enantiopure building block. The key feature of the present approach is to allow complete control of all the stereoge