56475-13-9Relevant academic research and scientific papers
The Reactivity of 2-Substituted Cyclohex-1-enecarboxylic Acid With Diazodiphenylmethane in Various Alcohols
Uscumlic, Gordana S.,Krstic, Vera V.,Muskatirovic, Milan D.
, p. 999 - 1002 (2007/10/02)
The reactivities of 2-substituted cyclohex-1-enecarboxylic acids with diazodiphenylmethane in several alcohols were investigated.The rate data for these acids were correlated with a simple Hammett equation by means of the ?p constants.The transmission of polar effects through the double bond, in terms of polar susceptibility constant ρ, has been discussed.For the reactions of a given acid in the various alcohols, the log k and ρ values were correlated through multiple regression on appropriate solvent parameters.The results obtained for 2-substituted cyclohex-1-enecarboxylic acids were compared with the results for ortho-substituted benzoic acids under the same experimental conditions.
