565-81-1Relevant academic research and scientific papers
EFFICIENT SYNTHESES OF ENANTIOMERICALLY PURE L AND D-ALLOTHREONINES AND (S) AND (R) ISOSERINES
Pons, Dominique,Savignac, Monique,Genet, Jean-Pierre
, p. 5023 - 5026 (2007/10/02)
Both enantiomers of (S) 1 and (R) 2 isoserine as well (D) 3 and (L) 4 allothreonine are prepared optically pure in three steps by asymmetric Sharpless epoxidation of crotyl and allylic alcohols into 7-10 followed by an improved RuCl3/NaIO4/water oxidation procedure to low molecular weight glycidic acids 11-14 and epoxide opening by ammonia with (20-33 percent) overall yields.
OXIDATIVE DEGRADATION OF β- AND γ-AMINO ACIDS BY CONTACT GLOW DISCHARGE ELECTROLYSIS
Harada, Kaoru,Terasawa, Jun-ichi
, p. 441 - 444 (2007/10/02)
The degradation of β- and γ-amino acids in aqueous solutions by contact glow discharge electrolysis (CGDE) was studied.It was found that the reaction is actually a stepwise oxidative degradation by hydroxyl radical produced by CGDE.
