5650-67-9Relevant academic research and scientific papers
SYNTHESIS OF UNSATURATED BICYCLIC LACTONES AND ACETALS VIA PALLADIUM-PROMOTED CYCLIZATION OF CYCLIC ALLYLIC ALCOHOLS
Larock, Richard C.,Stinn, Dean E.
, p. 2767 - 2770 (2007/10/02)
Unsaturated bicyclic lactones are readily prepared by converting cyclic allylic alcohols to the corresponding α-chloromercurio acetate esters and reacting them with Li2PdCl4.The corresponding acetals can be synthesized directly by reaction of the allylic
TOSYLOXYLACTONIZATION OF ALKENOIC ACIDS WITH BENZENE
Shah, Mayur,Taschner, Michael J.,Koser, Gerald F.,Rach, Nancy L.
, p. 4557 - 4560 (2007/10/02)
benzene(1) reacts with 3-butenoic, 4-pentenoic, 5-hexenoic and 2-methyl-4-pentenoic acids in CH2Cl2 to give tosyloxyacetones and with trans-3-hexenoic and 2-cyclopenteneacetic acids to give unsaturated lactones. 5-Norbornene-endo-2-carboxylic acid with 1 gives a rearranged lactone while 5-norbornene-endo-2,3-dicarboxylic acid gives a bis-lactone.
