565184-54-5Relevant academic research and scientific papers
β-arylthio-α-chloroalkyl ethers - Novel 1,1-bis-electrophiles for geminal alkylation
Gromov, Alexey V.,Smit, William A.
, p. 1317 - 1322 (2006)
A novel protocol for geminal alkylation is suggested based upon the consecutive generation of two cationoid intermediates from the easily prepared adducts of arylsulfenyl chlorides and vinyl ethers. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Adducts of ArSCl with vinyl ethers or esters as synthones in geminal alkylation
Smit, William A.,Gromov, Alexei V.,Yagodkin, Elisey A.
, p. 21 - 23 (2007/10/03)
The in situ-prepared adducts of arylsulfenyl chloride and vinyl ethers (esters) were employed as synthetic equivalents of 1,1-bis-electrophiles in the Lewis acid-promoted reaction sequence with two different carbon nucleophiles resulting in the formation of geminal bisalkylation products.
