5653-11-2

Upstream product

• 2744-08-3 decahydroisoquinoline 
• 70-11-1 α-bromoacetophenone 
• 25131-60-6 2-phenacylisoquinolinium bromide 
• 119-65-3 isoquinoline 
• 91-21-4 1,2,3,4-tetrahydroisoquinoline 

Downstream Products

• 107182-86-5 (Z)-α-(1,2,3,4-Tetrahydro-2-isochinolyl)-acetophenonoxim 
• 82342-56-1 N-benzoyl-1,2,3,4-tetrahydroisoquinoline 
• 1642568-72-6 (10-methyl-9,11-dioxo-6,9,10,11-tetrahydro-5H-pyrrolo[3',4':3,4]pyrrolo[2,1-a]isoquinoline-3-yl)(phenyl)methanone 
• 1430733-51-9 C₂₇H₁₇N₃O₅ 
• 1430733-50-8 C₂₈H₂₀N₂O₄ 
• 1430733-49-5 C₂₇H₁₇BrN₂O₃ 
• 1430733-48-4 C₂₇H₁₈N₂O₃ 
• 87773-10-2 2-Phenyl-5,6-dihydro-imidazo<2,1-a>isochinolin 
• 107183-01-7 (Z)-2-(2-Hydroximino-2-phenyl-ethyl)-1,2,3,4-tetrahydro-1-isochinolin 
• 107182-90-1 2-Phenyl-6,7-dihydro-4H-isochino<2,1-e>-1,2,5-oxadiazin 
• 17721-97-0 2-(3,4-dihydro-1H-isoquinolin-2-yl)-1-phenyl-ethanone oxime 

Relevant academic research and scientific papers

Copper-catalyzed aerobic cyclizations of tetrahydroisoquinolines with bromoketones and alkenes for the synthesis of 5,6-dihydropyrrolo[2,1-a] isoquinolines

A new copper-catalyzed oxidative cyclization protocol was developed for the synthesis of 5,6-dihydropyrrolo[2,1-a]isoquinolines via a three-component reaction of tetrahydroisoquinolines with bromoketones and electron-deficient alkenes with air as a termin

C60-Bodipy dyad triplet photosensitizers as organic photocatalysts for photocatalytic tandem oxidation/[3+2] cycloaddition reactions to prepare pyrrolo[2,1-a]isoquinoline

C60-Bodipy hybrids exhibiting strong absorption of visible light and long-lived triplet excited states were used as photocatalysts for tandem oxidation/[3+2] cycloaddition of tetrahydroisoquinoline with N-phenylmaleimide to produce pyrrolo[2,1-a]isoquinolines. The reaction is substantially accelerated, compared to that catalyzed by Ru(bpy)3Cl2.

The Reactions of α-Arylsulfonoxy Ketones with Nucleophiles

α-(p-Nitrophenyl)sulfonoxy ketones can be converted to α-hydroxy ketals and α-hydroxy ketones by reaction with potassium carbonate and basic or acidic workup, respectively.They also react with amines to give α-amino ketones in high yields.Nonnucleophilic amines give an intramolecular aromatic substitution in the derived enolate.Factors which dictate the reaction patterns in these compounds are discussed.