565442-75-3Relevant academic research and scientific papers
ARE PHENYLHALOCARBENES AMBIPHILIC?
Moss, Robert A.,Lawrynowicz, Witold,Hadel, Linda M.,Hacker, Nigel P.,Turro, Nicholas J.,et al.
, p. 4125 - 4128 (1986)
In additions to simple alkenes and styrenes at 25 deg C, the selectivities of PhCF and PhCCl are best described as electrophilic.
Formation of polysubstituted chlorocyclopropanes from electrophilic olefins and activated trichloromethyl compounds
Oudeyer, Sylvain,Léonel, Eric,Paugam, Jean Paul,Sulpice-Gaillet, Christine,Nédélec, Jean-Yves
, p. 1583 - 1589 (2007/10/03)
Chlorocyclopropanes and bicyclic chlorocyclopropanes are prepared in non basic conditions by electroreductive or Mg-promoted Barbier activation of PhCCl3 or Cl3CCO2Me in the presence of acyclic or cyclic α,β-unsaturated ca
Cyclopropane formation via a simple barbier reaction in DMF
Oudeyer, Sylvain,Aaziz, Akima,Léonel, Eric,Paugam, Jean Paul,Nédélec, Jean-Yves
, p. 485 - 488 (2007/10/03)
Cyclopropanes are prepared in good yields via magnesium activation of polyhalomethyl compounds (dichlorodiphenylmethane, methyl trichloroacetate, α,α,α-trichlorotoluene, benzal chloride, benzal bromide) in the presence of activated olefins in DMF.
