5658-51-5Relevant articles and documents
A New Synthesis of 1-n-Alkyl-3,5-dimethoxybenzenes (Olivetol Dimethyl Ether and Homologs)
Azzena, Ugo,Denurra, Teresa,Fenude, Emma,Melloni, Giovanni,Rassu, Gloria
, p. 28 - 30 (2007/10/02)
An efficient method is reported for the synthesis of 1-n-alkyl-3,5-dimethoxybenzenes, useful intermediates in the synthesis of cannabinoids, from the readily available and cheap 3,4,5-trimethoxybenzoic acid.The key step is the electron-transfer induced highly regioselective demethoxylation of 1-n-alkyl-3,4,5-trimethoxybenzenes.