56616-18-3Relevant academic research and scientific papers
The Synthesis and Investigation of Liquid-Liquid Extraction Capability of N-Diphenylphosphino-N-ethylaniline and Its Chalcogenide Derivatives
Akku?lu,Sar??z
, p. 817 - 822 (2019)
The aminophosphine ligand was synthesized by the reaction of N-ethylaniline with chlorodiphenylphosphine in the presence of triethylamine at low temperature. Oxidation of the ligand with elemental sulfur or selenium afforded the corresponding aminophosphi
REARRANGEMENT PHOSPHASEMIDINE D'UNE ANILINOPHOSPHINE PAR CATALYSE AVEC LE NICKEL(II)
Cristau, Henri-Jean,Chabaud, Bernard,Chene, Alain,Christol, Henri
, p. 55 - 64 (2007/10/02)
The arylation of N-ethylanilinodiphenylphosphine by bromobenzene in presence of catalytical amounts of nickel(II) affords a mixture of rearranged phosphonium salts from which, p-ethylaminophenyltriphenylphosphonium bromide has been isolated.A phosphasemidine type rearrangement takes place on the N-ethylanilinodiphenylphosphine.The latter, heated in presence of catalytical amounts of nickel(II), is converted to the p-ethylaminophenyldiphenylphosphine and an isomeric ethylaminophenyldiphenylphosphine whose structure is probably ortho.The structural identifications of these two phosphines have been done on the phosphines themselves and on their following derivatives: p-ethylaminophenylmethyldiphenylphosphonium iodide, ethylaminophenyldiphenylphosphine oxides.
