56617-35-7Relevant articles and documents
The Formation of CCl4- in Gamma Radiolysis of Methylcyclohexane(MCH)-CCl4 at 4.2 K
Suwalski, Jan P.,Kroh, Jerzy
, p. 267 - 274 (2007/10/02)
The formation and decay of species produced in MCH/CCl4 by ionizing radiation have been studied at 4.2 K.The optical spectrum consists of two bands: one narrow peak centered around 354 nm is attributed to CCl4- anion, the other weak band at 420-435 nm is assigned to CCl4+ cation.The spectra of the samples warmed from 4.2 K up to 77 K have been analysed.The formation of CCl4-, CCl4+, CCl3 and CCl4Cl and their role in the mechanism of the reaction occurring in the irradiated MCH/CCl4 system is discussed.