56670-83-8Relevant articles and documents
SELECTIVITY IN THE SULFONATION OF 1,5- AND 1,8-DIHYDROXY-ANTHRAQUINONES AND THEIR BORATE COMPLEXES
Gorelik, M. V.,Nevmyvako, V. P.,Tkachenko, S. S.
, p. 1500 - 1506 (2007/10/02)
As follows from determination of the rate constants, 1,5-dihydroxyanthraquinone surpasses 1,8-dihydroxyanthraquinone and also 1-hydroxyanthraquinone in the ease of sulfonation at the ortho position to the hydroxy group but is consumed much more slowly during sulfonation in sulfuric acid or oleum as a result of the higher basicity, which gives rise to a lower concentration of the reactive unprotonated form.The addition of boric acid completely prevents sulfonation of 1,5-dihydroxyanthraquinone, which is combined into an inert diborate complex, whereas in the form of a monoborate complex 1,8- dihydroxyantraquinone can be converted selectively into 1,8-dihydroxyanthraquinone-2-sulfonic acid.