566942-55-0

Basic information

• Product Name: [(bis(2-diphenylphosphinoethyl)phenylphosphine)Ni(CN-2,6-Me₂C₆H₃)]
• CAS NO: 566942-55-0
• Molecular Weight: 724.424
• Mol File: 566942-55-0.mol

Chemical Properties

• CAS DataBase Reference: [(bis(2-diphenylphosphinoethyl)phenylphosphine)Ni(CN-2,6-Me₂C₆H₃)](CAS DataBase Reference)
• NIST Chemistry Reference: [(bis(2-diphenylphosphinoethyl)phenylphosphine)Ni(CN-2,6-Me₂C₆H₃)](566942-55-0)
• EPA Substance Registry System: [(bis(2-diphenylphosphinoethyl)phenylphosphine)Ni(CN-2,6-Me₂C₆H₃)](566942-55-0)

Safety Data

• Hazardous Substances Data: 566942-55-0(Hazardous Substances Data)

Upstream product

• 1295-35-8 bis(1,5-cyclooctadiene)nickel ⁽⁰⁾ 
• 119072-54-7 2,6-dimethylphenyl isonitrile 
• 23582-02-7 bis(2-diphenylphosphinoethyl)phenylphosphine 

Relevant articles and documents

Efficient synthesis of N-aryl nickel(II) carbenes by protonation of nickel(0) isocyanide complexes

The new nickel isocyanide complex [Ni(tri-phos)(CN-xylyl)] (1) has been prepared by the reaction of Ni(COD)2, triphos (triphos = bis(2-diphenylphosphi-noethyDphenylphosphine), and CN-xylyl (xylyl = 2,6-Me2C6H3). Complex 1 adds 2 equiv of HBF4 to afford a stable dicationic nickel carbene complex, [Ni(triphos)C(H)N(H)xylyl]2+(BF4)2- (2), in high yield. Nickel carbene 2 exhibits transfer hydrogenation of ketones.