566950-11-6

Upstream product

• 566949-99-3 (R)-[(R)-2-methoxy-1-phenylethyl]-(1-phenylbuta-2,3-dienyl)amine 
• 144302-38-5 (R)-benzylidene-(2-methoxy-1-phenylethyl)amine 
• 566950-10-5 (R)-2-Phenyl-2-((R)-1-phenyl-buta-2,3-dienylamino)-ethanol 

Downstream Products

• 2941-19-7 (R)-1-phenylbutylamine 

Relevant academic research and scientific papers

Asymmetric Propargylboration of Aldimines and Ketimines with the Borabicyclo[3.3.2]decanes: Novel Entries to Allenyl Carbinamines, Amino Acids, and Their α-Methyl Counterparts

Available in either enantiomerically pure form through quantitative Grignard procedures from air-stable crystalline complexes (1, 3), the B-γ-TMS propargylic derivatives of the 10-TMS- (2) and 10-phenyl-9-borabicyclo[3.3.2]decanes (4) provide highly selec

Asymmetric synthesis of allyl- and α-allenylamines from chiral imines and alkynes via (η2-imine)Ti(O-i-Pr)2 complexes

(Matrix presented) The reaction of a divalent titanium reagent Ti(O-i-Pr)4/2i-PrMgX with optically active arylaldimines derived from arylaldehydes and O-methylphenylglycinol provided, in a highly diastereoselective manner, chiral (η2-imine)Ti(O-i-Pr) 2 complexes, which in turn reacted with 1-alkynes or propargyl compounds to give optically active allyl- and α-allenylamines, respectively.