56717-56-7Relevant academic research and scientific papers
Deoxygenation of sulfoxides, selenoxides, telluroxides, sulfones, selenones and tellurones with Mg-MeOH
Khurana, Jitender M.,Sharma, Vandana,Chacko, Silvi A.
, p. 966 - 969 (2007)
The deoxygenation of a variety of sulfoxides, selenoxides, telluroxides, sulfones, selenones and tellurones has been reported with Mg-MeOH at room temperature in nearly quantitative yields. The deoxygenation is proposed to proceed by SET from Mg to the substrate.
Synthesis and characterization of alkyl aryl selenides from arylselenomagnesium halides
Bhasin, K K,Gupta, Vijay,Bari, S S,Sharma, R P
, p. 635 - 637 (2007/10/02)
Arylselenomagnesium halides, ArSeMgX, obtained by the reaction of elemental selenium with arylmagnesium halides, react with alkyl halides to afford alkyl aryl selenides in good yields.This constitutes a relatively simpler and convenient method for the preparation of a number of unsymmetrical selenides.The compounds prepared have been characterized by elemental analysis, IR, 1H NMR, 13C NMR and mass spectral studies.
