5672-50-4Relevant academic research and scientific papers
Perfluorinated cyclic and acyclic keto-enol systems: A remarkable contrast
Lindner, Patrick E.,Lemal, David M.
, p. 3259 - 3266 (2007/10/03)
Recent reports from this laboratory have revealed that highly fluorinated 4- and 5-membered-ring enols are comparable in stability to, or more stable thermodynamically than, the corresponding ketones, even in non-Lewis-basic media. Work on perfluorinated
REACTION OF POLYFLUORINATED DERIVATIVES OF BENZENE CONTAINING HYDROGEN ATOMS IN THE SIDE CHAIN WITH VANADIUM PENTAFLUORIDE
Avramenko, A. A.,Bardin, V. V.,Karelin, A. I.,Krasil'nikov, V. A.,Tushin, P. P.,et al.
, p. 2318 - 2323 (2007/10/02)
The treatment of C6F5R (R=CH3, CH2F, CHF2) compounds with vanadium pentafluoride at -25 to -30 deg C leads to a 1-R-heptafluoro-1,4-cyclohexadienes, 1-R-nonafluorocyclohexenes, and products form fluorination of the side chain.Fluorination of the anisole derivatives C6F5OCH3 and C6F5OCHF2 only takes place in the aromatic ring.
