56799-24-7Relevant articles and documents
The first total synthesis of (+)-mucosin
Henderson, Alan R.,Stec, Jozef,Owen, David R.,Whitby, Richard J.
supporting information; experimental part, p. 3409 - 3411 (2012/05/20)
The first total synthesis of (+)-mucosin has been completed allowing assignment of the absolute stereochemistry of the natural product. A zirconium induced co-cyclisation was utilised to install the correct stereochemistry of the four contiguous stereocentres around the unusual bicyclo[4.3.0]nonene core.
Chemoselectivity and unusual internal acetal formation in the synthesis of a glycosidation precursor
Stevens, Anne T.,Bull, James R.,Chibale, Kelly
, p. 3175 - 3179 (2008/09/19)
Chemoselective deprotection of a tert-butyldimethyl (TBS) silyl ether group in the presence of an acetal moiety within an advanced iridoid precursor using scandium trifluoromethane-sulfonate at 25°C unexpectedly leads to internal acetal formation in high
217. Enantioselective Syntheses and Absolute Configurations of Viridiene and Aucantene, Two Constituents of Algae Pheromone Bouquets
Boland, Wilhelm,Niedermeyer, Uwe,Jaenicke, Lothar,Goerisch, Helmut
, p. 2062 - 2073 (2007/10/02)
Viridiene ((+)-6; (+)-(3R,4S)-3-((1Z)-1,3-butadienyl)-4-vinylcyclopentene) and aucantene ((+)-18; (+)-(4R,5R)-4-((1E)-1-propenyl)-5-vinylcyclohexene) are constituents of the pheromone bouquets of several brown algae species.Key synthons to the title compo
