5682-67-7Relevant academic research and scientific papers
Lone selectivity of the decatungstate-sensitized photooxidation of 1-substituted cycloalkenes
Lykakis, Ioannis N.,Orfanopoulos, Michael
, p. 2131 - 2134 (2007/10/03)
Decatungstate-sensitized oxidation of alkyl and phenyl substituted cycloalkenes in the presence of molecular oxygen shows a general preference for hydrogen abstraction on the congested side of the double bond.
α-Oxidation of ketones using n-cation radicals
Schulz, Manfred,Kluge, Ralph,Sivilai, Li,Kamm, Birgit
, p. 2371 - 2380 (2007/10/02)
Six-membered ring ketones and acyclic ketones were oxidized by stable triarylamminium radical cations in moist acetonitrile at room temperature in the presence of a base to α-hydroxy ketones in good yield. Five-membered ring ketones gave the corresponding αβ-unsaturated compounds.
ON THE SYNTHESIS AND CONFORMATIONAL ASPECTS OF 2-METHYL AND 2-t.BUTYL SUBSTITUTED 1,3-CYCLOPENTANE AND CYCLOHEXANE DIOLS
D'Haenens, L.,Sande, C. C. Van de,Tavernier, D.,Vandewalle, M.
, p. 273 - 282 (2007/10/02)
The diastereomers of 2-methyl-1,3-cyclopentanediol, 2-t.butyl-1,3-cyclopentanediol, 2-methyl-1,3-cyclohexanediol and 2-t.butyl-1,3-cyclohexanediol have been prepared.Configurational assignment and some conformational aspects are described.
